82390-29-2Relevant academic research and scientific papers
Geometrically Biased Homoconjugated Ketones. Synthetic Avenues to 1-Acyl-2,4-cyclohexadienes
Fuchs, Benzion,Zizuashvili, Jakob,Abramson, Sarah
, p. 3474 - 3477 (1982)
Synthetic approaches to a series of open (1), fused (2), and spiroannelated (3) 2,4-cyclohexadien-1-yl ketones, which differ in the geometrical juxtaposition of the homoconjugated chromophores, have been worked out.A series of prototropic rearrangements was found to occur, establishing an equilibrium between 28-30.
