82415-93-8Relevant academic research and scientific papers
A facile indium-mediated synthesis of protected and unprotected [1- (hydroxymethyl)vinyl]alkanols
Moirangthem, Nimalini D.,Thingom, Bhavna,Laitonjam, Warjeet S.
experimental part, p. 455 - 459 (2009/12/24)
Protected and unprotected [l-(hydroxymethyl)vinyl]alkanols (7 and 8) have been synthesized from the homologated y-hydroxy esters 4 which have been prepared by indium-mediated allylation of the rearranged bromides 3 derived from hydroxyl esters 2 in water medium.
PREPARATION AND SYNTHETIC APPLICATION OF 2-BROMOALLYLTRIMETHYLSILANE AS A 1-HYDROXYMETHYLVINYL ANION EQUIVALENT
Nishiyama, Hisao,Yokoyama, Hiroshi,Narimatsu, Shinzo,Itoh, Kenji
, p. 1267 - 1270 (2007/10/02)
The 1-trimethylsilylmethylvinyl group, as a 1-hydroxymethylvinyl equivalent, was readily introduced to epoxides with the corresponding Grignard reagent derived from 2-bromoallyltrimethylsilane.Obtained 2-(2-hydroxyethyl)-allylsilanes were converted to α-methylene-γ-lactones via diols.
