82428-94-2Relevant academic research and scientific papers
Hafnium (IV) Dithiocarbamates
Kumar, Shyam,Kaushik, N. K.
, p. 182 - 184 (2007/10/02)
Mono-, bis-, tris- and tetrakis-dithiocarbamatohafnium(IV) complexes of the type Hf(dtc)nCl4-n where n = 1,2,3 or 4; dtc = N-ethyl, N-m-tolyl; N-cyclopentyl and N-cycloheptyl dithiocarbamate ligands have been prepared and characterised on the basis of elemental analyses, molecular weight, conductance, magnetic moment, IR and PMR spectral studies.All the complexes are monomeric, diamagnetic and nonelectrolytic in nature.The dithiocarbamate ligands behave as typical bidentate ligands and hence, in the present complexes, hafnium (IV) can be assigned 5,6,7 and 8 coordination numbers when n = 1,2,3 and 4 respectively.
