82431-50-3Relevant academic research and scientific papers
Highly Regioselective Allylation of α-Enones and Epoxides with Lithium Tetraallyllanthanoid Ate Complex
Fukuzawa, Shin-ichi,Sakai, Shizuyoshi
, p. 3308 - 3314 (2007/10/02)
Tetraallyllanthanoid ate complex (1), which was readily prepared in situ from tetraallyltin, lanthanoid trichloride, and butyllithium in tetrahydrofuran (THF), reacts smoothly with α-enones (3-11) with a high degree of 1,2-regioselectivity (1,2:1,4 = >99:
?-Allyl Lanthanoid Ate Complex as a New Highly 1,2-Regioselective Allyl Transfer Agent for α,β-Unsaturated Carbonyl Compounds
Fukuzawa, Shin-ichi,Sato, Ken,Fujinami, Tatsuo,Sakai, Shizuyoshi
, p. 939 - 940 (2007/10/02)
The ?-allyl lanthanoid ate complex (1), which was prepared in situ from tetra-allyltin, the lanthanoid trichloride, and n-butyl-lithium in tetrahydrofuran (THF), reacts smoothly with α,β-unsaturated carbonyl compounds (3) - (11) with a high degree of 1,2-
CARBON-CARBON BOND FORMATION WITH METALLIC MANGANESE
Hiyama, Tamejiro,Sawahata, Miwa,Obayashi, Michio
, p. 1237 - 1238 (2007/10/02)
Metallic manganese is found to reduce allylic bromides and achieve the Barbier-type carbonyl addition of allyl unit.
