82461-89-0Relevant academic research and scientific papers
REDUCTIONS ELECTROCHIMIQUES ET CHIMIQUES DE PHENYL-2 6H-THIAZINES-1,3
Jubault, Michel,Tallec, Andre',Bujoli, Bruno,Roze', Jean-Claude,Pradere, Jean-Paul
, p. 745 - 748 (1985)
Electrochemical and chemical reductions of 2-phenyl 6H-1,3-thiazines are complementary methods for the regioselective hydrogenation of the heterocyclic structure.
REGIOSELECTIVE ELECTROREDUCTION OF 6H-1,3-THIAZINES. COMPARISON WITH CHEMICAL REDUCTIONS I - INVESTIGATION OF 2-PHENYL-6H-1,3-THIAZINES
Bujoli, Bruno,Jubault, Michel,Roze, Jean-Claude,Tallec, Andre
, p. 2709 - 2720 (2007/10/02)
The electrochemical reduction of 2-phenyl-6H-1,3-thiazines carried out at a mercury cathode in acetate buffer + ethanol (1:1) has been studied: - In the case of compounds monoactivated at carbon 5 (R5 = CHO or COCH3) either hydrodimers (resulti
Reduction Regioselective de Phenyl-2 6H-Thiazines-1,3 Substituees en 5 par des Groupements Fonctionnels Electroattracteurs
Pradere, Jean-Paul,Roze, Jean-Claude,Duguay, Guy
, p. 901 - 911 (2007/10/02)
Sodium cyanoborohydride, triethylsilane (acidic medium), and aluminium amalgam (basic medium) regioselectively reduce the intracyclic imine group whereas sodium borohydride transforms the carbonyl fonction at position 5 into an alcohol.
