82470-74-4Relevant articles and documents
Synthetic Studies on Quassinoids: Total Synthesis of (+/-)-Shinjulactone C
Collins, Jon L.,Grieco, Paul A.,Gross, Raymond S.
, p. 5816 - 5818 (2007/10/02)
The total synthesis of the novel quassinoid Shinjulactone C (1) is detailed which proceeds via pentacyclic lactone 3 and features new protocols for elaboration of the ring A 1β-hydroxy-2-oxo-Δ3,4 olefin unit and the C(8),C(11) bridged hemiketal array which are present in 3 and common to numerous quassinoids.