82472-60-4Relevant academic research and scientific papers
Arene exchange in the ruthenium-naphthalene complex [CpRu(C 10H8)]+
Perekalin, Dmitry S.,Karslyan, Eduard E.,Petrovskii, Pavel V.,Borissova, Alexandra O.,Lyssenko, Konstantin A.,Kudinov, Alexander R.
, p. 1485 - 1492 (2012)
Substitution of the naphthalene ligand in [CpRu(C10H 8)]+ (1; Cp = cyclopentadienyl ligand) by other arenes occurs upon heating or visible-light irradiation and gives complexes [CpRu(arene)]+ [arene = C6/s
SYNTHESIS AND CHARACTERISATION OF THE MIXED SANDWICH CATIONS + (M=Ru, Os)
Robertson, I.W.,Stephenson, T.A.,Tocher, D.A.
, p. 171 - 178 (2007/10/02)
The published reaction of 2> with Tl to give Cl has been extended to other 2> complexes to provide a convenient, high yield route to the + cations (M = Ru; arene = C6H6,p-MeC6H4CHMe2, C6H5OMe, C6Me6; M = Os; arene = C6H6, p-MeC6H4CHMe2).Electrochemical studies and some reactions of these complexes are also described.
