82475-35-2Relevant academic research and scientific papers
The "benzostabase" protecting group for primary amines; application to aliphatic amines
Bonar-Law,Davis,Dorgan,Reetz,Wehrsig
, p. 6725 - 6728 (2007/10/02)
The "benzostabase" (BSB) protecting group has been applied to primary aliphatic amines. It can be introduced via a dehydrogenative silylation employing an air- and moisture-stable reagent, and is appreciably more acid-stable than the related "stabase" group. BSB protection has been used in a stereoselective synthesis of amino-alcohols involving the addition of organometallic reagents to protected amino-aldehydes under "non-chelation control".
REACTIONS DE L'ortho-BIS(DIMETHYLSILYL)BENZENE AVEC LES NITRILES CATALYSEES PAR DES COMPLEXES DU RHODIUM
Corriu, R. J. P.,Moreau, J. J. E.,Pataud-Sat, M.
, p. 301 - 308 (2007/10/02)
The silylation reaction of nitriles using a bis-hydrosilane has been studied.The reaction of 1,2-bis(dimethylsilyl)benzene in the presence of as catalyst leads to a mixture of trans-N,N-disilated enamines and N,N-disilylated amines, the rati
