82485-86-7Relevant academic research and scientific papers
Metal-assisted reactions. Part 26.1 Catalytic reactivity and ether bond lengths in aryloxytetrazoles and aryloxypseudosaccharins
Alves, Jose A. C.,Barkley, James V.,Brigas, Amadeu F.,Johnstone, Robert A. W.
, p. 669 - 677 (2007/10/03)
X-Ray structure determinations on a variety of aryloxytetrazoles 1 and aryloxypseudosaccharins 4 have shown that the central C-O-C ether linkage is remarkable in having one very long C-O bond and one very short one. The central C-O-C bond angle is close t
Metal-assisted Reactions: Part 19. Burst Kinetics in Heterogeneous Catalytic Transfer Hydrogenolysis
Johnstone, Robert A. W.,Price, Peter J.
, p. 1069 - 1076 (2007/10/02)
Arene formation by catalytic transfer hydrogenolysis of aryloxytetrazolyl ethers in the liquid-phase shows biphasic concentration-time curves which indicate rate-limiting dissociation of heterogeneous complexes between catalyst and one of the reaction products, a tetrazolone.A dependence of catalytic reaction rate on pH and following modifications made to the catalyst are reported also.
