82494-87-9Relevant academic research and scientific papers
Silicon in Synthesis. 21. Reagents for Thiophenyl-Functionalized Cyclopentenone Annulations and the Total Synthesis of (+/-)-Hirsutene
Magnus, Philip,Quagliato, Dominick
, p. 1621 - 1626 (2007/10/02)
1-(Trimethylsilyl)-1-(phenylthio)ethylene (1) reacts with cyclic α,β-unsaturated acid chlorides to give β-mercaptophenyl-substituted cyclopentenones, whereas 1-(trimethylsilyl)-2-(phenylthio)ethylene (2) under similar conditions results in thiophenyl migr
