825-03-6

Usage

Uses

Used in Pharmaceutical Industry:
2-METHYLBICYCLO[2.2.1]-5-HEPTENE-2-CARBOXYLIC ACID is used as a potential active pharmaceutical ingredient for its possible biological activities, which may include medicinal properties that could be harnessed for the development of new drugs.
Used in Agrochemical Industry:
In the agrochemical sector, 2-METHYLBICYCLO[2.2.1]-5-HEPTENE-2-CARBOXYLIC ACID is used as a potential component in the development of new pesticides or herbicides, leveraging its chemical properties to control or eliminate unwanted plant species.
Used in Materials Science:
2-METHYLBICYCLO[2.2.1]-5-HEPTENE-2-CARBOXYLIC ACID is utilized as a building block in the synthesis of new materials with unique properties, such as advanced polymers or composites, for applications in various industries.

InChI:InChI=1/C9H12O2/c1-9(8(10)11)5-6-2-3-7(9)4-6/h2-3,6-7H,4-5H2,1H3,(H,10,11)/p-1/t6-,7-,9-/m1/s1

Upstream product

• 79-41-4 poly(methacrylic acid) 
• 542-92-7 cyclopenta-1,3-diene 
• 77-73-6 bi(cyclopentadiene) 
• 40441-67-6 5-formyl-5-methylbicyclo[2.2.1]hept-2-ene 

Downstream Products

• 100869-68-9 (+/-)-5,6,7,8-tetrachloro-2-methyl-(4at,8at)-1,2,3,4,4a,5,8,8a-octahydro-1r,4c;5t,8t-dimethano-naphthalene-2ξ-carboxylic acid 
• 58055-94-0 ((1S,4S)-2-Methyl-bicyclo[2.2.1]hept-5-en-2-yl)-methanol 
• 91573-15-8 Toluene-4-sulfonic acid (1S,4S)-2-methyl-bicyclo[2.2.1]hept-5-en-2-ylmethyl ester 

Relevant academic research and scientific papers

Functional norbornanyl ester derivatives, polymers and process for preparing same

This invention relates to the new functional norbornanyl ester derivative and/or polymer compositions which are easily obtainable by reacting the Diels-Alder adduct of appropriate dienes and dienophiles with carboxylic acids. In particular, this invention relates to a new process for making cyclic chemical raw materials suitable for production coating, ink, adhesive, plasticizer, thermoplastic or thermosetting plastic and functional polymers.

Enantioselective diels-alder reactions with anomalous endo/exo selectivities using conformationally flexible chiral supramolecular catalysts

Swapped selectivities: The use of tailor-made catalysts results in anomalous endo/exo selectivities and high enantioselectivities in the Diels-Alder reactions of cyclopentadiene with different acroleins (see scheme). These supramolecular catalysts are prepared in situ from chiral diols, arylboronic acid, and tris(pentafluorophenyl)borane, and can discriminate the re/si face of the dienophile as well as the endo/exo approach of the diene.

Synthesis of a 1,3-spiro-amino-alcohol-derived chiral auxiliary and its application to Diels-Alder reactions

A short synthesis and resolution of (1R,5R,6R)-6-aminospiro[4.4]nonan-1-ol, 11, is reported. The pivalamide derivative (+)-5 gives excellent diastereo- and regiocontrol as well as endo selectivity as a chiral auxiliary in the BCl3-catalyzed Die

Asymmetric Hetero Diels-Alder Reaction Catalyzed by Stable and Easily Prepared CAB Catalysts

A stable chiral (acyloxy)borane (CAB) complex is prepared in situ by mixing tartaric acid derivative and arylboric acid at room temperature.A solution of the catalyst is effective to catalyze hetero Diels-Alder reaction to produce dihydropyrone derivative

Acyloxyborane: An Activating Device for Carboxylic Acids

We chose α,β-unsaturated acids and investigated the reactivity of their borane adducts in Diels-Alder reactions.The reaction did proceed smoothly and has been found to be a useful method for synthesis of carboxylic acids.