82507-35-5

Upstream product

• 82507-49-1 (4S,5S)-3-<(2R,3S,4S)-1-oxo-2,4,6-trimethyl-3-hydroxyhept-6-enyl>-4-methyl-5-phenyloxazolidin-2-one 
• 82507-34-4 (4R,5S)-3-((2R,3S,4S,6R)-7-Hydroxy-2,4,6-trimethyl-3-trimethylsilanyloxy-heptanoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 80719-70-6 (4R,5S)-3-<(2S)-1-oxo-2,4-dimethylpent-4-enyl>-4-methyl-5-phenyloxazolidin-2-one 
• 158930-33-7 (4R,5S)-(CHCH₃CHPhOCONCOB(n-Bu)2CHCH₃) 
• 82507-33-3 (4R,5S)-4-Methyl-5-phenyl-3-((2R,3S,4S)-2,4,6-trimethyl-3-trimethylsilanyloxy-hept-6-enoyl)-oxazolidin-2-one 
• 82507-47-9 (S)-(-)-2,4-dimethylpent-4-en-1-ol 
• 82507-48-0 (S)-(+)-2,4-dimethylpent-4-enal 

Downstream Products

• 69056-12-8 (+)-Prelog-Djerassi lactonic acid 
• 82507-36-6 (4R,5S)-3-[(R)-2-((2S,3S,5R)-3,5-Dimethyl-6-oxo-tetrahydro-pyran-2-yl)-propionyl]-4-methyl-5-phenyl-oxazolidin-2-one 

Relevant academic research and scientific papers

Stereoselective Reactions of Chiral Enolates. Application to the Synthesis of (+)-Prelog-Djerassi Lactonic Acid

The application of chiral metal enolates 3 and 4 have been employed in an efficient synthesis of (+)-Prelog-Djerassi lactone (1).

Acyclic Diastereoselection in the Hydroboration Process. Documented Cases of 1,3-Asymmetric Induction

Good levels of 1,3-asymmetric induction have been observed in the hydroboration of terminal olefins (eq. 1).A considerable level of generality has been noted in this reaction and a transition state model has been proposed to account for the observations.