82510-56-3

Upstream product

• 73093-19-3 3,4-dihydroxy-3,4-dihydrobenzo[c]phenanthrene 
• 86631-73-4 (3R,4R)-3,4-Dihydro-benzo[c]phenanthrene-3,4-diol 
• 86602-27-9 ((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-acetic acid (3R,4R)-3-[2-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-acetoxy]-3,4-dihydro-benzo[c]phenanthren-4-yl ester 
• 80285-08-1 3-hydroxybenzophenanthrene acetate 
• 118658-88-1 benzophenanthrene-3,4-dione 
• 22717-95-9 3-hydroxybenzophenanthrene 

Downstream Products

• 79117-81-0 (3R,4S)-3,4-Dihydroxy-3,4-dihydro-1H-benzo[c]phenanthren-2-one 
• 79117-82-1 (1S,2R,3R,4S)-1,2,3,4-Tetrahydro-benzo[c]phenanthrene-1,2,3,4-tetraol 
• 79117-82-1 (1S,2S,3S,4R)-1,2,3,4-Tetrahydro-benzo[c]phenanthrene-1,2,3,4-tetraol 
• 945548-64-1 N²-[1-(2,3,4-trisbenzoyloxy-1,2,3,4-tetrahydrobenzo[c]phenanthrenyl)]-O⁶-benzyl-3',5'-bis-O-(tert-butyldimethylsilyl)-2'-deoxyguanosine 
• 945548-63-0 N⁶-[1-(2,3,4-trisbenzoyloxy-1,2,3,4-tetrahydrobenzo[c]phenanthrenyl)]-3',5'-bis-O-(tert-butyldimethylsilyl)-2'-deoxyadenosine 

Relevant academic research and scientific papers

An Efficient Synthesis of the Highly Tumorigenic anti-Diol Epoxide Derivative of Benzophenanthrene

Synthesis of the potent tumorigen trans-3,4-dihydroxy-anti-1,2,3,4-tetrahydrobenzophenanthrene (1) in relatively few steps and superior overall yield is described.The method entails synthesis of the key intermediate 3-hydroxybenzophenanthrene (7b) v

SYNTHESIS AND ASSIGNEMENT OF ABSOLUTE CONFIGURATION TO THE TRANS 3,4-DIHYDRODIOLS AND 3,4-DIOL-1,2-EPOXIDES OF BENZOPHENANTHRENE

The (+)- and (-)-trans-3,4-dihydroxy-3,4-dihydrobenzophenanthrenes have been resolved and assigned absolute configuration by independent nmr and CD methods.Each was converted to its pair of diastereomeric bay-region 3,4-diol-1,2-epoxydes in which the b