82590-62-3

Upstream product

• 117701-85-6 ((2S,3R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-2-benzyloxy-tetrahydro-pyran-3-yl)-trimethyl-ammonium; bromide 
• 117701-84-5 ((2S,3R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-2-benzyloxy-tetrahydro-pyran-3-yl)-trimethyl-ammonium; iodide 
• 117701-86-7 ((2S,3R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-2-benzyloxy-tetrahydro-pyran-3-yl)-trimethyl-ammonium; chloride 

Relevant academic research and scientific papers

UEBER EINE UNGEWOEHNLICHE REAKTION DER 2-DESOXY-2-TRIMETHYLAMMONIO-D-GLUCOSE

The alkaline hydrolysis of 2-deoxy-1,3,4,6-tetra-O-acetyl-2-trimethylammonio-α-D-glucopyranose chloride leads to an unexpected product.Contrary to the hydrolysis under acidic conditions yielding 2-deoxy-2-trimethylammonio-D-glucose we obtained the corresponding 3,6-anhydro derivative by reaction with sodium hydroxide or ammonia in methanol.