82590-72-5Relevant academic research and scientific papers
SYSNTHESIS OF (CH3C(CH2PPh2)3)CoL COMPLEXES (L=O2CO, S2CO, O2SO) THROUGH METAL-ASSISTED CO2, CS2, SO2 OXIDATION. CRYSTAL STRUCTURE OF (CH3C(CH2PPh2)3)Co(O2SO)
Cecconi, Franco,Ghilardi, Carlo A.,Midollini, Stefano,Moneti, Simonetta,Orlandini, Annabella
, p. C5 - C9 (2007/10/02)
The solution obtained by reduction of 2+ (triphos=CH3C(CH2PPh2)3) with Na/Hg reacts with CO2, CS2 and SO2 to give (triphos)Co(O2CO), (triphos)Co(S2CO), and (triphos)Co(O2SO), respectively.The molecular structure o
Reactivity of η2-CS3Me Metal Complexes as Electrophiles
Bianchini, Claudio,Meli, Andrea
, p. 2419 - 2424 (2007/10/02)
The CS2 carbon atom of the η2-CS3Me ligand in the cobalt(II) and nickel(II) complexes is an electrophilic centre, susceptible to attack by nucleophil
