82591-09-1Relevant academic research and scientific papers
Insertion of Carbon Dioxide and of Unsaturated Carbon Compounds into the Platinum-Nitrogen Bond: the X-Ray Crystal Structure of cyclo>(PPh3)2
Bellon, Pier Luigi,Cenini, Sergio,Demartin, Francesco,Pizzotti, Maddalena,Porta, Francesca
, p. 265 - 266 (2007/10/02)
Pt(PhNO)(PPh3)2 reacts with unsaturated carbon compounds such as carbon dioxide, carbon disulphide, alkenes, and dimethyl acetylenedicarboxylate to give 1:1 adducts; X-ray studies on the adduct formed with carbon dioxide, cyclo>(PPh3)2, show that the entering molecule is inserted into the platinum-nitrogen bond of the η2-bonded nitroso ligand.
