82653-45-0

Basic information

• Product Name: (2R,3R,2'S,3'S)-bis-(4-acetyl-2,3-dihydro-5-methyl-3-phenyl-2-furyl)hydroxylamine
• CAS NO: 82653-45-0
• Molecular Weight: 433.504
• Mol File: 82653-45-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3R,2'S,3'S)-bis-(4-acetyl-2,3-dihydro-5-methyl-3-phenyl-2-furyl)hydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,2'S,3'S)-bis-(4-acetyl-2,3-dihydro-5-methyl-3-phenyl-2-furyl)hydroxylamine(82653-45-0)
• EPA Substance Registry System: (2R,3R,2'S,3'S)-bis-(4-acetyl-2,3-dihydro-5-methyl-3-phenyl-2-furyl)hydroxylamine(82653-45-0)

Safety Data

• Hazardous Substances Data: 82653-45-0(Hazardous Substances Data)

Upstream product

• 123-54-6 acetylacetone 
• 5153-67-3 nitrostyrene 
• 72709-61-6 (+/-)-3-(2-nitro-1-phenylethyl)pentane-2,4-dione 

Downstream Products

• 63324-73-2 1-(2-methyl-4-phenyl-1H-pyrrol-3-yl)ethan-1-one 
• 81675-24-3 (2R,3R,2'S,3'S)-O-acetylbis-(4-acetyl-2,3-dihydro-5-methyl-3-phenyl-2-furyl)hydroxylamine 

Relevant articles and documents

Unusual Michael Reaction of Acyclic 1,3-Dicarbonyl Compounds with Nitro-olefins. A Novel Pyrrole Synthesis

Acetoacetic esters and pentane-2,4-dione undergo unusual Michael reactions with β-nitrostyrene in methanol-sodium methoxide to form the (2R,3R,2'S,3'S)-bis-(4-acyl-2,3-dihydro-5-methyl-3-phenyl-2)-furylhydroxylamines (5) in high yields.The normal adducts