82660-92-2

Upstream product

• 1271-66-5 dimethyltitanocene 
• 80611-26-3 [FeCl(CO)3((CH₃)3P)2]⁽¹⁺⁾*[B(C₆H₅)4]^(1-)=[FeCl(CO)3((CH₃)3P)2][B(C₆H₅)4] 

Downstream Products

• 89557-62-0 [Fe(CO)2(P(CH₃)3)2(P(OCH(CH₃)2)3)(COCH₃)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Fe(CO)2(P(CH₃)3)2(P(OCH(CH₃)2)3)(COCH₃)][B(C₆H₅)4] 
• 89557-56-2 [Fe(CO)2(P(CH₃)3)2(C₅H₄NNH₂)(CH₃)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Fe(CO)2(P(CH₃)3)2(C₅H₄NNH₂)(CH₃)][B(C₆H₅)4] 
• 60685-73-6 [Fe(CO)2(P(CH₃)3)2(CH₂CHCN)(CH₃)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Fe(CO)2(P(CH₃)3)2(CH₂CHCN)(CH₃)][B(C₆H₅)4] 
• 89557-52-8 [Fe(CO)2(P(CH₃)3)2(P(CH₂CH₃)3)(CH₃)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Fe(CO)2(P(CH₃)3)2(P(CH₂CH₃)3)(CH₃)][B(C₆H₅)4] 
• 89557-60-8 [Fe(CO)2(P(CH₃)3)2(P(OCH₃)3)(COCH₃)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Fe(CO)2(P(CH₃)3)2(P(OCH₃)3)(COCH₃)][B(C₆H₅)4] 
• 89557-58-4 [Fe(CO)2(P(CH₃)3)3(COCH₃)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Fe(CO)2(P(CH₃)3)3(COCH₃)][B(C₆H₅)4] 
• 89616-73-9 {Fe(CO)2(P(CH₃)3)2(NCCH₃)CH₃}⁽¹⁺⁾*B(C₆H₅)4^(1-)={Fe(CO)2(P(CH₃)3)2(NCCH₃)CH₃}B(C₆H₅)4 

Relevant academic research and scientific papers

Reactions of Methyl Complexes of Iron(II) with Lewis Bases

The ionic complex reacts with Lewis bases (L) to give .Two reaction paths are observed: one involving carbon monoxide insertion followed by attack of the L ligand, and a second in which ligand exchange is followed by an insertion reaction.The relative importance of the two paths depends on the nature and the concentration of L.The neutral complexes also react with Lewis bases to give .When X=I the acetyl complex is readily transformed into the corresponding ionic methyl complex I.The neutral complexes react faster than the ionic ones.The structure of the ionic and neutral complexes has been assigned on the basis of i.r. and n.m.r. evidence.

PHOTOCHEMICALLY INDUCED TRANSMETHYLATION IN TRANSITION METAL COMPOUNDS USING METHYLTITANOCENES

Photolysis of dimethyltitanocene and chloromethyltitanocene in the presence of another transition metal complex leads to methyl transfer from titanium to transition metal and to other ligand transfer reactions.These reactions are thought to proceed by a free radical pathway.