82680-22-6Relevant academic research and scientific papers
Synthesis of 2-ethynylaziridines
Shubina,Tikhomirov,Eremeev
, p. 494 - 498 (2007/10/02)
2-Ethynyl-substituted aziridines were obtained by the reaction of acetylenic β-amino and β-azido alcohols with triphenylphosphine and carbon tetrachloride in the presence of triethylamine. The cycloaddition of carbenes and diazomethane to an acetylenic imine was investigated. 2-Ethynylaziridines were obtained in the case of carbonylalkoxycarbenes. The regioselectivity of the cycloaddition of carbenes to an acetylenic imine is demonstrated.
