82704-23-2

Basic information

• Product Name: (Z)-1-Methylthio-1,5-hexadiene
• Synonyms: (Z)-1-Methylthio-1,5-hexadiene
• CAS NO: 82704-23-2
• Molecular Weight: 128.238
• Mol File: 82704-23-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-Methylthio-1,5-hexadiene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-Methylthio-1,5-hexadiene(82704-23-2)
• EPA Substance Registry System: (Z)-1-Methylthio-1,5-hexadiene(82704-23-2)

Safety Data

• Hazardous Substances Data: 82704-23-2(Hazardous Substances Data)

Upstream product

• 19159-56-9 3-Methylthio-1,5-hexadiene 

Relevant articles and documents

Cope Rearrangements of Donor Substituted 1,5-Hexadienes

Alkoxy, alkylthio, and dialkylamino groups in position 3 of 1,5-hexadiene and in position 2 of 3,3-dimethyl-1,5-hexadiene have rather small effects on the Cope rearrangement (maximum rate acceleration by a factor of 60; maximum ΔEa = 5,5 kcal/mol = 23 kJ/mol).The pattern of substituent effects is more consistent with a diradicaloid mechanism than with a concerted sigmatropic rearrangement.