82719-54-8

Basic information

• Product Name: 1-methyl-4-[(2-methyl-3-butyn-2-yl)oxy]benzene
• Synonyms: 1-methyl-4-[(2-methyl-3-butyn-2-yl)oxy]benzene
• CAS NO: 82719-54-8
• Molecular Weight: 174.243
• Mol File: 82719-54-8.mol

Chemical Properties

• CAS DataBase Reference: 1-methyl-4-[(2-methyl-3-butyn-2-yl)oxy]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-4-[(2-methyl-3-butyn-2-yl)oxy]benzene(82719-54-8)
• EPA Substance Registry System: 1-methyl-4-[(2-methyl-3-butyn-2-yl)oxy]benzene(82719-54-8)

Safety Data

• Hazardous Substances Data: 82719-54-8(Hazardous Substances Data)

Upstream product

• 106-44-5 p-cresol 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 1111-97-3 3-chloro-3-methylbut-1-yne 

Downstream Products

• 106-44-5 p-cresol 
• 122323-12-0 1-(3-Bromo-1,1-dimethyl-prop-2-ynyloxy)-4-methyl-benzene 

Relevant articles and documents

Variation in the aromatic ring of cromakalim: Antihypertensive activity of pyranopyridines and 6-alkyl-2H-1-benzopyrans

The synthesis and antihypertensive activity in the spontaneously hypertensive rat of two new series of analogues related to cromakalim (1) are described. In the first series, where the benzopyran nucleus has been replaced by a pyranopyridine nucleus, the

Benzopyran derivatives and processes for preparation thereof

Benzopyrene derivatives effective for the treatment of hypertension have been prepared.

A FACILE SYNTHESIS OF ARYL ETHERS OF ETHYNYLCARBINOLS USING THE MITSUNOBU REACTION

The facile synthesis of a few aryl ethers of ethynylcarbinols using the Mitsunobu reaction is reported.

THERMAL AND CATALYTIC REARRANGEMENTS OF 4-(1,1-DIMETHYL-2-PROPENOXY)TOLUENE

During the thermal and catalytic rearrangements of 4-(1,1-dimethyl-2-propenoxy)toluene the Claisen phenol, with inversion of the allyl unit, i.e., 4-methyl-2-(3-methyl-2-butenyl)phenol, is formed primarily.The formation of 2-methyl-2-(3-methyl-2-butenyl)phenol in the catalytic rearrangement with the introduction of o-cresol into the reaction zone shows that this rearrangement has partly intermolecular character.Consequently, the Claisen phenol can also be obtained by an intermolecular path, where this phenol is the most thermodynamically stable isomer.