82721-70-8Relevant articles and documents
An Efficient Electrochemical Route to (Perfluoroalkyl)alkynes
Calas, Patrick,Moreau, Patrice,Commeyras, Auguste
, p. 433 - 434 (1982)
Electrocatalytic addition of perfluoroalkyl iodides to 3-hydroxy-3-alkylbut-1-ynes, followed by dehydroiodination and thermal cleavage in basic medium, leads to an easy and efficient preparation of (perfluoroalkyl)alkynes.
Addition d'iodoperfluoroalcanes RFI (CnF2n+1, n = 4, 6, 8) au 2-methyl-3-butyn-2-ol catalysee par le zinc dans differents solvants. Application a la synthese de l'acetylenique a chaine perfluoree
Abou-Ghazaleh, B.,Laurent, Ph.,Blancou, H.,Commeyras, A.
, p. 21 - 24 (1994)
The addition of perfluoroalkyl iodides (RFI) to 2-methyl-3-butyn-2-ol activated by suspended zinc dust has been studied in different solvents and found to lead readily to perfluoroalkene iodides.The latter when treated with a base gave a perfluoroalkyne, RFCCH.