82726-79-2

Basic information

• Product Name: Ethanone, 2,2,2-trifluoro-1-(2-hydroxy-1-cyclohexen-1-yl)- (9CI)
• Synonyms: Ethanone, 2,2,2-trifluoro-1-(2-hydroxy-1-cyclohexen-1-yl)- (9CI)
• CAS NO: 82726-79-2
• Molecular Formula: C₈H₉F₃O₂
• Molecular Weight: 194.1510696
• Product Categories: ACETYLHALIDE
• Mol File: 82726-79-2.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 2,2,2-trifluoro-1-(2-hydroxy-1-cyclohexen-1-yl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2,2,2-trifluoro-1-(2-hydroxy-1-cyclohexen-1-yl)- (9CI)(82726-79-2)
• EPA Substance Registry System: Ethanone, 2,2,2-trifluoro-1-(2-hydroxy-1-cyclohexen-1-yl)- (9CI)(82726-79-2)

Safety Data

• Hazardous Substances Data: 82726-79-2(Hazardous Substances Data)

Upstream product

• 1190130-75-6 2-bromo-2-(trifluoroacetyl)cyclohexanone 
• 1190130-76-7 2-chloro-2-(trifluoroacetyl)cyclohexanone 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 187726-38-1 2,2,2-Trifluoro-1-(2-pyrrolidin-1-yl-cyclohex-1-enyl)-ethanone 

Downstream Products

• 1190130-75-6 2-bromo-2-(trifluoroacetyl)cyclohexanone 
• 1190130-76-7 2-chloro-2-(trifluoroacetyl)cyclohexanone 
• 25666-51-7 2-trifluoroacetylphenol 

Relevant articles and documents

Halogenation of fluorinated cyclic 1,3-dicarbonyl compounds: new aspects of synthetic application

In order to elaborate on an approach towards 2-(fluoroacyl)phenols being the superior alternative to the conventional Fries-rearrangement based methodology, the behaviour of cyclic fluorinated 1,3-dicarbonyls in reactions with halogenating agents was examined. The synthetic relevance of the polyhalogenated compounds obtained was demonstrated by the synthesis of several new heterocycles. An aromatization via a halogenation-dehydrohalogenation sequence proved to be a rewarding synthetic route to 2-(fluoroacyl)phenols and previously unknown 3-(fluoroacyl)thiochromones. The structure of one of the synthesized compounds was confirmed by X-ray diffraction analysis.