827346-03-2Relevant academic research and scientific papers
Preparation and coordination chemistry of N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine
Slawin, Alexandra M.Z.,Milton, Heather L.,Wheatley, Joanne,Woollins, J. Derek
, p. 3125 - 3132 (2008/10/09)
N-diallylaminodiphenylphosphine coordinates using P, N or CC whereas N-allylaminobis(diphenylphosphine)phosphine is a simple P donor. N-diallylaminodiphenylphosphine and N-allylaminobis(diphenyl)phosphine have been prepared by reaction of the appropriate amine with Ph2PCl. The coordination chemistry of these phosphines has been studied with a range of metals [Pd, Pt, Rh, Ir, Au, Ru, Mo]. Whilst the majority of the complexes are simple bidentate P,P donors, in the case of N- diallylaminodiphenylphosphinecoordination can involve the CC group or the nitrogen centre.
