827609-98-3

Basic information

• Product Name: Rh₂(((C₆H₅)2PC₂H₄O)2C₁₄H₈)(((C₆H₅)2PC₂H₄S)2C₆H₄)(CO)2Cl₂
• CAS NO: 827609-98-3
• Molecular Weight: 1534.14
• Mol File: 827609-98-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rh₂(((C₆H₅)2PC₂H₄O)2C₁₄H₈)(((C₆H₅)2PC₂H₄S)2C₆H₄)(CO)2Cl₂(CAS DataBase Reference)
• NIST Chemistry Reference: Rh₂(((C₆H₅)2PC₂H₄O)2C₁₄H₈)(((C₆H₅)2PC₂H₄S)2C₆H₄)(CO)2Cl₂(827609-98-3)
• EPA Substance Registry System: Rh₂(((C₆H₅)2PC₂H₄O)2C₁₄H₈)(((C₆H₅)2PC₂H₄S)2C₆H₄)(CO)2Cl₂(827609-98-3)

Safety Data

• Hazardous Substances Data: 827609-98-3(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 75-57-0 tetramethlyammonium chloride 

Relevant articles and documents

Heteroligated metallomacrocycles generated via the weak-link approach

Sequential reaction of two different hemilabile ligands (Ph 2PCH2-CH2X)2Ar (X = S, Ar = C 6H4 or C6(CH3)4; X = NCH3, Ar = C6H4; X = O, Ar = 9,10-C 14H8) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [(1,4-(Ph2PCH2CH2S) 2C6H4)-{1,4-(Ph2PCH 2CH2S)2C6(CH3) 4}Rh2](BF4)2, as determined by X-ray crystallography, is presented.