82763-96-0

Basic information

• Product Name: Germole, 1,1,3,4-tetramethyl-
• Synonyms: Germole, 1,1,3,4-tetramethyl-
• CAS NO: 82763-96-0
• Molecular Formula: C₈H₁₄Ge
• Molecular Weight: 0
• Mol File: 82763-96-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 170.5°C at 760 mmHg
• Flash Point: 46.2°C
• Appearance: /
• Vapor Pressure: 1.94mmHg at 25°C
• CAS DataBase Reference: Germole, 1,1,3,4-tetramethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Germole, 1,1,3,4-tetramethyl-(82763-96-0)
• EPA Substance Registry System: Germole, 1,1,3,4-tetramethyl-(82763-96-0)

Safety Data

• Hazardous Substances Data: 82763-96-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H14Ge/c1-7-5-9(3,4)6-8(7)2/h5-6H,1-4H3

Upstream product

• 82763-89-1 tetramethyl-1,1,3,4 germacyclopentene-4 ol-3 
• 82763-91-5 trimethyl-1,1,3 methylene-4 germacyclopentanol-3 
• 103-71-9 phenyl isocyanate 
• 94890-82-1 1,1,3,4-tetramethyl-3-(phenylcarbamoyl)-1-germacyclopent-4-ene 

Downstream Products

• 104439-74-9 Co((CH₃)4H₂C₄Ge)(P(CH₃)3)3⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Co((CH₃)4H₂C₄Ge)(P(CH₃)3)3]B(C₆H₅)4 

Relevant articles and documents

Electronic structure of group 14 (η4-metallole)tricarbonyliron complexes

Some methyl derivatives of metalloles R2XC4H4 (X = C, Si, Ge) and their tricarbonyliron complexes have been prepared in order to study the influence of both the group 14 elements and complexation effects on the electronic structure of the diene ring using photoelectron spectroscopy (UPS, He I, He II). Strong electron donation from iron to the metallole ligand has been demonstrated. This transfer, which is the result of participation of the lowest vacant orbital of the ring (3b1) in the highest occupied orbital (HOMO) of the complex, shows that these compounds have a certain aromatic character.