82764-08-7Relevant articles and documents
Isolation & Reaction of a New Arsonium Ylid: 2,7-Dichlorofluorenylidenetriphenylarsenane
Gupta, K. C.,Nigam, R. K.
, p. 241 - 242 (2007/10/02)
A new stabilized arsonium ylid, 2,7-dichlorofluorenylidenetriphenylarsenane (2) has been reacted with a variety of substituted benzaldehydes to give 2,7-dichloro-9-arylidenefluorenes.Similarly, the ylid (2) also couples with furfural and cinnamaldehyde to give 2,7-dichloro-9-furfurylidenefluorene and 2,7-dichloro-9-cinnamylidenefluorene in good yields.Bis-fluorenylidene derivatives are obtained when 2 reacts with isophthalaldehyde or terephthalaldehyde.The products have been characterised by elemental analyses, IR and PMR data.