82797-60-2

Basic information

• Product Name: heptyl 2,4,6-triisopropylthiobenzoate
• CAS NO: 82797-60-2
• Molecular Weight: 362.62
• Mol File: 82797-60-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: heptyl 2,4,6-triisopropylthiobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: heptyl 2,4,6-triisopropylthiobenzoate(82797-60-2)
• EPA Substance Registry System: heptyl 2,4,6-triisopropylthiobenzoate(82797-60-2)

Safety Data

• Hazardous Substances Data: 82797-60-2(Hazardous Substances Data)

Upstream product

• 1639-09-4 heptanethiol 
• 57199-00-5 2,4,6-triisopropylbenzoyl chloride 
• 49623-71-4 2,4,6-triisopropylbenzoic acid 

Downstream Products

• 82797-61-3 2'-hydroxy-2'-methyl-3'-nonyl 2,4,6-triisopropylthiobenzoate 
• 82797-62-4 1'-hydroxy-1'-phenyl-2'-octyl 2,4,6-triisopropylthiobenzoate 

Relevant articles and documents

Dipole-Stabilized Carbanions from Thioesters. Secondary α'-Lithio Carbamates and Tertiary α'-Lithio Thioesters

The formation of 5 and 17, synthetic equivalents of the α-lithioalkylthio and α-lithiodialkylthio functions, respectively, by deprotonations of the corresponding carbamate 4 and thioester 16 are reported.The reactions of these formally dipole-stabilized carbanions with a variety of electrophiles and their use in synthese of 2,3-substituted thiiranes are demonstrated.The rearrangement of 17 to an α-thiol ketone is shown to be intramolecular by a double labeling experiment.Potentially chiral or conformationally isomeric α'-lithio thioesters are found to be racemized and equilibrated.Formations of secondary α'-lithio thioesters in medium chain, β'-dimethylamino, and allyl systems are reported while β'-alkoxy groups are shown to eliminate to give vinyl thio esters which undergo further metalation.The kinetic acidity of a methyl thioester is shown to be comparable to a propenyl thioester and greater then an ethyl thioester.