82811-33-4Relevant academic research and scientific papers
The Oxidative Properties of Nitroxy-radicals in Their Reactions with Sterically Hindered Hydroxylamines
Dikanov, S. A.,Grigor'ev, I. A.,Volodarskii, L. B.,Tsvetkov, Yu. D.
, p. 1696 - 1699 (2007/10/02)
A relative scale of the oxidative properties of cyclic nitroxy-radicals has been constructed and the influence of various structural factors on the oxidising capacity of the nitroxy-group in the radicals has been investigated.It is shown that the oxidative properties of the nitroxy-group in cyclic nitroxy-radicals become more pronounced with the increase in ring size.A relation has been established between the oxidative properties and the electron-accepting properties of functional groups separated from the nitroxy-group by two and more ?-bonds.
