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4-methyl-N-[(6-oxo-1-cyclohexa-2,4-dienylidene)methyl]benzohydrazide is a complex organic compound with the molecular formula C16H15N3O3. It is a derivative of benzohydrazide, featuring a methyl group at the 4-position and a cyclohexa-2,4-dienylidene moiety attached to the nitrogen atom. 4-methyl-N-[(6-oxo-1-cyclohexa-2,4-dienylidene)methyl]benzohydrazide is characterized by its unique structure, which includes a 6-oxo group within the cyclohexa-2,4-dienylidene ring, contributing to its chemical properties and potential applications. It is often used in the synthesis of various pharmaceuticals and agrochemicals due to its reactivity and ability to form stable intermediates in chemical reactions.

82859-74-3

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  • 4-methyl-N-[(6-oxo-1-cyclohexa-2,4-dienylidene)methyl]benzohydrazide

    Cas No: 82859-74-3

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82859-74-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 82859-74-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,2,8,5 and 9 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 82859-74:
(7*8)+(6*2)+(5*8)+(4*5)+(3*9)+(2*7)+(1*4)=173
173 % 10 = 3
So 82859-74-3 is a valid CAS Registry Number.

82859-74-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-methyl-N'-[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]benzohydrazide

1.2 Other means of identification

Product number -
Other names N-salicylidene-p-methylbenzoylhydrazine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:82859-74-3 SDS

82859-74-3Relevant articles and documents

X-ray structurally characterized Mo (VI), Fe (III) and Cu (II) complexes of amide-imine conjugate: (bio)catalytic and histidine recognition studies

Ta, Sabyasachi,Ghosh, Milan,Salam, Noor,Das, Jayanta,Islam, Manirul,Brand?o, Paula,Félix, Vítor,Sanmartin, Jesus,Das, Debasis

, (2020/07/13)

An amide-imine conjugate, (E)-N′-((2-hydroxybenzen-1-yl) methylene)-4-methylbenzohydrazide (H2LPTASAL), derived from 4-methyl-benzoic acid hydrazide (PTA) and 2-hydroxybenzaldehyde is used to prepare Mo (VI), Cu (II) and Fe (III) complexes. The X-ray structurally characterized complexes have been explored as catalyst for amine assisted asymmetric ring opening (ARO) of epoxide, carbon-heteroatom cross-coupling and ethyl benzene oxidation. In addition, their catecholase like activities have thoroughly been investigated. Moreover, the Cu (II) complex selectively recognizes histidine by fluorescence spectroscopy.

Tetrabromomethane as an Organic Catalyst: a Kinetic Study of CBr4-Catalyzed Schiff Condensation

Bolotin, Dmitrii S.,Kukushkin, Vadim Yu.,Tolstoy, Peter M.,Vovk, Mikhail A.,Yunusova, Sevilya N.

supporting information, p. 6763 - 6769 (2020/10/27)

Tetrabromomethane functions as an organic catalyst for non-redox reactions of carbonyl species and, in particular, it enhances the aldehyde–acyl hydrazide condensation to give N-acyl hydrazones. This simple, inexpensive, and commercially available halomet

Synthesis, crystal structures of oxovanadium(V) complexes with hydrazone ligands and their catalytic performance for the styrene oxidation

Zhang, Yan,Yang, Ting,Zheng, Bo-Yang,Liu, Ming-Yang,Xing, Na

, p. 123 - 129 (2016/11/11)

Four new oxovanadium(V) complexes, [VO(aha)L1] (1), [VO(aha)L2] (2), [VO(aha)L3] (3), and [VO(aha)L4]·EtOH (4) (Haha?=?acetohydroxamic acid, H2L1?=?4-nitrophenyl 2-(2-hydroxybenzylidene)hyd

Binuclear copper complexes: Synthesis, X-ray structure and interaction study with nucleotide/protein by in vitro biochemical and electrochemical analysis

Alagesan,Bhuvanesh,Dharmaraj

, p. 281 - 293 (2014/04/17)

Two new, binuclear copper(II) hydrazone complexes have been synthesized and characterized by various physico-chemical techniques including single crystal X-ray diffraction. Interaction of these complexes with nucleotide and protein were analyzed by in vit

Synthesis and X-ray structural characterization of dioxomolybdenum(VI) complexes with N'-(5-chloro-2-hydroxybenzylidene)-4-methylbenzohydrazide and N'(2-hydroxybenzylidene)-4-methylbenzohydrazide

Lei,Fu

experimental part, p. 65 - 70 (2012/03/26)

Two new dioxomolybdenum(VI) complexes, [MoO2(ClHm)(CH 3OH)] (I) and [MoO2(Hm)(CH3OH)] (II) with the hydrazone ligands H2ClHm and H2Hm derived from 4-methylbenzohy-drazide with 5-chlorosalicylaldehyde and salicylaldehyde, respectively, have been synthesized and structurally characterized by physicochemical methods and single-crystal X-ray determination. The crystal of I crystallizes in the triclinic space group $Πbar 1$$, with a = 7.839(2), b = 9.656(3), c = 11.548(4) A α = 88.885(3)°, β = 87.454(3)°, γ = 88.996(3)°, V = 873.0(5) A3, Z = 2, R 1 = 0.0292, wR 2 = 0.0685, S = 1.092. The crystal of II crystallizes in the triclinic space group $Πbar 1$$, with a = 7.780(2), b = 10.584(3), c = 10.628(3) A, α = 91.462(3)°, β = 104.818(3)°, γ = 103.288(3)°, V = 820.1(4) A3, Z = 2, R 1 = 0.0403, wR 2 = 0.0784, S = 1.065. An X-ray analysis indicates that the structures of both complexes are similar to each other. The molybdenum atom in each complex is in an octahedral coordination environment constructed by two oxo groups, an NO2 donor set of the hydrazone ligand, and one methanol O atom.

Effect of substitution and planarity of the ligand on DNA/BSA interaction, free radical scavenging and cytotoxicity of diamagnetic Ni(ii) complexes: A systematic investigation

Sathyadevi, Palanisamy,Krishnamoorthy, Paramasivam,Butorac, Rachel R.,Cowley, Alan H.,Bhuvanesh, Nattamai S. P.,Dharmaraj, Nallasamy

experimental part, p. 9690 - 9702 (2011/12/13)

Four new bivalent nickel hydrazone complexes have been synthesised from the reactions of [NiCl2(PPh3)2] with H 2L {L = dianion of the hydrazones derived from the condensation of salicylaldehyde or o-hydroxy acet

SYNERGISTIC FUNGICIDAL COMPOSITIONS INCLUDING HYDRAZONE DERIVATIVES AND COPPER

-

Page/Page column 28, (2010/08/08)

The present invention relates to the use of mixtures containing hydrazone compounds and copper for controlling the growth of fungi.

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