82881-09-2Relevant articles and documents
SYNTHESIS OF dl-CORIOLIN
Ito, Toshio,Tomiyoshi, Nobuya,Nakamura, Koki,Azuma, Shizuo,Izawa, Makoto,et al.
, p. 241 - 255 (2007/10/02)
The total synthesis of dl-coriolin has been achieved in a stereoselective way.The key tricyclic intermediate was synthesized from dicyclopentadiene through a route which involved an SN2 reaction at a neopentylic position.
THE SYNTHESIS OF dl-CORIOLIN
Schuda, Paul Francis,Heimann, Martha R.
, p. 2365 - 2380 (2007/10/02)
The synthesis of dienone 2, which has previously been converted into the title compound in one step, is described.The methanoindene 7 is transformed into dienone-alcohol 58 in eighteen steps (12percent overall yield).This was then hydroxylated at C-8, usi
THE SYNTHESIS OF d,l-CORIOLIN
Shuda, Paul Francis,Heimann, Martha R.
, p. 4267 - 4270 (2007/10/02)
The formal synthesis of coriolin (1) from methanoindene 2 is described.
A NEW SYNTHESIS OF dl-CORIOLIN A. APPLICATION OF A NEW SN2 REACTION AT A NEOPENTYLIC POSITION
Ito, Toshio,Tomiyoshi, Nobuya,Nakamura, Koki,Azuma, Shizuo,Izawa, Makoto,et. al
, p. 1721 - 1724 (2007/10/02)
Dicyclopentadiene has been stereoselectively converted to a key tricyclic intermediate for the total synthesis of coriolin, through a route which involves a new SN2 reaction at a neopentylic position.