82884-25-1Relevant academic research and scientific papers
On the Mechanism and Scope of a Novel Nitroolefin Rearrangement
Hassner, Alfred,Chau, William
, p. 1989 - 1992 (2007/10/02)
D-Labelling permits differentiation between three plausible mechanistic pathways in the novel transformation of vinylaziridene 1 with β-nitrostyrene 4 to nitro enamino olefin 5.The results are consistent with a retro-ene reaction proceeding under mild conditions (80 deg C).Choice of proper substituents can guide the reaction toward formation of azepines or substituted enamines.
