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The chemical compound "V(CO)3(NO)((C6H5)2PCH2P(C6H5)2)" is a vanadium-based complex with a unique structure. It features a vanadium (V) atom at its center, coordinated to three carbonyl (CO) ligands, one nitrosyl (NO) ligand, and a bidentate diphosphine ligand, which is a derivative of diphenylphosphine. The diphosphine ligand, ((C6H5)2PCH2P(C6H5)2), consists of two phenyl groups (C6H5) attached to phosphorus atoms that are connected by a methylene bridge (CH2). V(CO)3(NO)((C6H5)2PCH2P(C6H5)2) is of interest in organometallic chemistry and catalysis due to its potential applications in various chemical transformations, particularly those involving the activation of small molecules like carbon monoxide and nitrogen oxide.

82887-67-0

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82887-67-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 82887-67-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,2,8,8 and 7 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 82887-67:
(7*8)+(6*2)+(5*8)+(4*8)+(3*7)+(2*6)+(1*7)=180
180 % 10 = 0
So 82887-67-0 is a valid CAS Registry Number.

82887-67-0Upstream product

82887-67-0Downstream Products

82887-67-0Relevant academic research and scientific papers

PHOSPHIN-STABILISIERTE CARBONYLNITROSYLVANADIUM-VERBINDUNGEN: DARSTELLUNG UND SPEKTROSKOPISCHE EIGENSCHAFTEN

Schiemann, Jan,Weiss, Erwin,Naeumann, Fritz,Rehder, Dieter

, p. 219 - 228 (1982)

Numerous new complexes of the type V(CO)5 - n(NO)Ln have been prepared either by nitrosylation of - (n = 2, 3) with NOX (X = Cl, BF4) and 2, resp., or by reaction of L with "V(CO)5NO" generated in situ.The compounds com

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