82887-85-2Relevant academic research and scientific papers
PREPARATION AND REPLACEMENT REACTIONS OF PENTACARBONYL(DIMETHYLSULFOXIDO)VANADATE(-I)
Ihmels, Klaus,Rehder, Dieter
, p. 151 - 154 (2007/10/02)
The photo-reaction between and DMSO yields (with DMSO presumably bonded via sulfur).Thermally induced replacement of DMSO by a ligand L affords , where L=pyridine, CN-, PCy3, Ph2As(CH2)2PPh2, Ph2P(CH2)2PPh2, Ph2P(CH2)2PEt2, PhP(CH2CH2PPh2)2 and P(CH2CH2PPh2)3.IR, 31P and 51V NMR spectra are reported.
