82895-44-1

Basic information

• Product Name: Pyridine, 2-[(1-butyl-3,7-dimethyl-2,6-octadienyl)thio]-, (E)-
• CAS NO: 82895-44-1
• Molecular Formula: C19H29NS
• Molecular Weight: 303.512
• Mol File: 82895-44-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-[(1-butyl-3,7-dimethyl-2,6-octadienyl)thio]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-[(1-butyl-3,7-dimethyl-2,6-octadienyl)thio]-, (E)-(82895-44-1)
• EPA Substance Registry System: Pyridine, 2-[(1-butyl-3,7-dimethyl-2,6-octadienyl)thio]-, (E)-(82895-44-1)

Safety Data

• Hazardous Substances Data: 82895-44-1(Hazardous Substances Data)

Upstream product

• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 92531-85-6 2-((phenylsulfonyl)methyl)prop-2-enylphenylsulfone 

Relevant articles and documents

A New Synthesis of Olefins via the Elimination Reaction of β-Tributylstannyl Organosulfur Compounds

Organosulfur compounds on treatment with butyllithium in tetrahydrofuran followed by tributylstannylmethyl iodide 1 afforded olefins.The reaction was found to proceed via the destannylsulfurization of the initially formed β-stannyl organosulfur compounds.Thus, allyl 2-pyridyl sulfides 2 or allyl phenyl sulfones 12 were converted into 1,3-dienes 4.Compounds 13 and 15 were converted into the olefins 14 and 17.Furthermore, the reaction was applied to the synthesis of α-substituted vinyl sulfides 24 and allene 27.The stereochemistry of the double bond is discussed.Keywords - destannylsulfurization; allyl 2-pyridyl sulfide; allyl phenyl sulfone; synthesis of olefin; 1,3-diene; vinyl sulfide; β-tributylstannyl organosulfur compound.