82912-81-0Relevant articles and documents
The indium(III) chloride-catalysed hydrolysis and in situ Mukaiyama-type reaction of arylmethyl ketone derived silyl enol ethers under solvent-free conditions
Chancharunee, Sirirat,Perlmutter, Patrick,Statton, Maya
, p. 5683 - 5685 (2003)
Treatment of trimethylsilyl enol ethers of arylmethyl ketones with catalytic amounts of indium(III) chloride under solvent-free conditions leads to a remarkably efficient process of in situ hydrolysis and Mukaiyama-type addition to the resulting ketones.
Some Aspects of the Reaction of Phenylselenomagnesium Bromide with Carbonyl Compounds
Kametani, Tetsuji,Aizawa, Masahiro,Kurobe, Hiroshi,Matsuura, Takahiro,Nemoto, Hideo,Fukumoto, Keiichiro
, p. 1493 - 1495 (2007/10/02)
The reactivity of phenylselenomagnesium bromide with some carbonyl compounds has been studied.It was found that aromatic aldehydes were reduced to give the corresponding alcohols, and aliphatic aldehydes and ketones which have active hydrogens were found to afford condensed products.Keywords---reactivity of phenylselenomagnesium bromide; reduction of aromatic aldehydes; condensing agents; organoselenium compounds; synthesis of aromatic alcohols