82921-67-3Relevant academic research and scientific papers
A MILD METHOD FOR THE SYNTHESIS OF ANOMERICALLY ALLYLATED C-GLYCOPYRANOSIDES AND C-GLYCOFURANOSIDES
Kozikowski, Alan P.,Sorgi, Kirk L.
, p. 2281 - 2284 (1982)
The reaction of glycosyl acetates with allyltrimethylsilane in the presence of zinc bromide has been investigated as a new method for C-glycoside construction.
Synthesis of the ABCD trioxadispiroketal subunit of azaspiracid-1: An iodoetherification-dehydroiodination strategy for complex spiroketals
Li, Xiaohua,Li, Jialiang,Mootoo, David R.
, p. 4303 - 4306 (2008/03/12)
An unusual spiroketalization strategy in which a hydroxyalkene serves as a precursor to a cyclic enol ether was applied to the synthesis of the ABCD trioxadispiroketal subunit of azaspiracid-1. The trioxadispiroketal product, which represents a double ano
Use of Allyltrimethylsilane in the Formation of Potential C-Nucleoside Precursors
Cupps, Thomas L.,Wise, Dean S.,Townsend, Leroy B.
, p. 5115 - 5120 (2007/10/02)
The soft nucleophile allyltrimethylsilane raeacted with 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose under Lewis acid catalysis to afford the novel allyl sugar 4,7-anhydro-1,2,3-trideoxy-5,6,8-tri-O-benzoyl-D-altro(allo)-oct-1-ene (1) as an anomeric mi
