82925-57-3Relevant academic research and scientific papers
A new platinum vapor-derived highly efficient hydrosilylation catalyst: NMR structural investigation
Uccello-Barretta, Gloria,Balzano, Federica,Evangelisti, Claudio,Raffa, Patrizio,Mandoli, Alessandro,Nazzi, Samuele,Vitulli, Giovanni
, p. 1276 - 1282 (2008/09/17)
The structural features of a highly efficient hydrosilylation catalyst generated by reaction of Pt vapor and a mixture of mesitylene and 1,3-divinyltetramethyldisiloxane (DVS) were investigated by mono- and bidimensional NMR analyses. The structure around the Pt atoms was highlighted and compared with a commercial sample (Karstedt catalyst) and previously reported Pt vapor-derived system.
Platinum oxide (PtO2): A potent hydrosilylation catalyst
Sabourault, Nicolas,Mignani, Gerard,Wagner, Alain,Mioskowski, Charles
, p. 2117 - 2119 (2007/10/03)
(matrix presented) Platinum oxide was found to be a versatile and powerful hydrosilylation catalyst upon a wide variety of functionalized alkenes and especially aminated alkenes. Moreover, highly reproducible results and easy removal make this new catalys
