82947-19-1

Basic information

• Product Name: 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene
• Synonyms: 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene
• CAS NO: 82947-19-1
• Molecular Weight: 404.533
• Mol File: 82947-19-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene(82947-19-1)
• EPA Substance Registry System: 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene(82947-19-1)

Safety Data

• Hazardous Substances Data: 82947-19-1(Hazardous Substances Data)

Upstream product

• 4485-91-0 1-(p-methylphenylamino)-3-(p-methylphenylimino)-1-propene 
• 121-44-8 triethylamine 
• 98-59-9 p-toluenesulfonyl chloride 
• 106-49-0 p-toluidine 
• 62-53-3 aniline 
• 82947-20-4 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-butene 
• 82947-21-5 1-(N-phenylcarbamoyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene 
• 78486-46-1 1-(N-benzoyl-p-methylphenyloamino)-3-(p-methylphenylimino)-1-propene 
• 78486-47-2 l-(N-benzoyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-butene 
• 59360-12-2 1-(N-acetyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene 
• 135523-42-1 1-(p-methylphenylamino)-3-(p-methylphenylimino)-1-butene 

Downstream Products

• 3085-54-9 N-(4-methylphenyl)formamide 
• 599-86-0 4-methyl-N-(4-methylphenyl)benzenesulfonamide 
• 51217-92-6 β-(p-toluidino)acrolein 
• 106-49-0 p-toluidine 
• 4485-91-0 1-(p-methylphenylamino)-3-(p-methylphenylimino)-1-propene 
• 82947-22-6 β-(N-tosyl-p-toluidino)acrolein 
• 1967-26-6 N-(4-chlorophenyl)-N'-phenylurea 
• 582-78-5 N-(4-methylphenyl)benzamide 
• 83583-90-8 1-(p-methylphenylamino)-3-(p-chlorophenylimino)-propene 
• 83583-88-4 β-(N-phenylcarbamoyl-p-toluidino)-acrolein 
• 82947-21-5 1-(N-phenylcarbamoyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene 

Relevant articles and documents

Hydrolysis of Aryl Derivates of Malonaldehyde Dianil. III

The reaction sequence of hydrolysis of N-acyl derivates of malonaldehyde dianil was examined.Hydrichloric acid-catalysed hydrolysis occured at the imino group to form arylamine and β-(N-acylarylamino)acrolein; the latter compound is not stable in acid solution.In the case of 1-(N-phenylcarbamoyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene, hydrolysis occured at both the imino and the carbamoyl groups.Buffer catalysed hydrolysis occured at the imino group, and the resulting β-(N-acylarylamino)acrolein and arylamine reacted to form β-arylaminoacrolein and N-arylamine.The aminolysis reaction was suppressed in hydrochloric acid-catalysed hydrolysis.Alkaline hydrolysis of N-acyl derivates of malonaldehyde dianil and of β-arylaminoacrolein occured at the amide carbonyl group except in the case of 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenylimino)-1-propene.N-tosyl-p-toluidine was obtained in this case.Keywords--hydrolysis; malonaldehyde dianil; β-arylaminoacrolein; 1-(N-acylarylamino)-3-arylamino-1-propene; β-(N-acylarylamino)acrolein; 1-(N-tosyl-p-methylphenyilamino)-3-(p-methylphenylimino)-1-propene; 1-(N-tosyl-p-methylphenylamino)-3-(p-methylphenyilimino-1-butene; β-(N-tosyl-p-toluidino)acrolein; 4-(N-tosyl-p-toluidino)-3-buten-2-one