83025-77-8Relevant academic research and scientific papers
THE VINYLOGOUS CONIA REARRANGEMENT : A MASKED ENE REACTION
Kende, Andrew S.,Newbold, Ronald C.
, p. 4329 - 4332 (2007/10/02)
A novel carbocyclic thermal rearrangement of 4-substituted 2-cyclohexen-1-ones is suggested to involve a 'masked' ene reaction and provides a facile route to spirocyclic cyclohexenone systems.
Intramolecular Photocyclizations. 2. Total Synthesis of (+/-)-Hibiscone C (Gmelofuran)
Koft, Emil R.,Smith, Amos B.
, p. 2115 - 2121 (2007/10/02)
We describe here a full account of the first total synthesis of (+/-)-hibiscone C (gmelofuran) (1), a structurally novel furanosesquiterpene isolated from the heartwood of Hibiscus elatus (Blue Mahoe), the national tree of Jamaica.The synthesis proceeds i
