83032-23-9

Upstream product

• 61865-88-1 3-O-(3,4-didesoxy-6-O-trityl-α-D-glycero-hex-3-enopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 83032-24-0 3-O-(2-acetoximino-3,4-di-O-acetyl-6-O-trityl-α-D-lyxo-hexopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 491-85-0 3-O-(2-acetamido-2-desoxy-α-D-talopyranosyl)-D-glucose 
• 491-85-0 O-3-(2-acetamido-2-desoxy-α-D-galactopyranosyl)-D-glucose 
• 83032-26-2 Acetic acid (2R,3S,4S,5R,6S)-4-acetoxy-5-acetylamino-6-[(3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy]-2-trityloxymethyl-tetrahydro-pyran-3-yl ester 
• 83032-29-5 3-O-(2-acetamido-3,4-di-O-acetyl-2-desoxy-6-O-trityl-α-D-galactopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 83032-25-1 3-O-(2-Acetamido-3,4-di-O-acetyl-2-desoxy-6-O-trityl-α-D-talopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 83032-25-1 3-O-(2-Acetamido-2-desoxy-6-O-trityl-α-D-galactopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 83032-28-4 3-O-(2-acetamido-3-O-acetyl-2-desoxy-6-O-trityl-α-D-galactopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 

Relevant academic research and scientific papers

SYNTHESE DE DISACCHARIDES A LIAISON α-D PAR CYCLOADDITION: 3-O-α-L-FUCOPYRANOSYL-D-GLUCOSE, 3-O-(2-ACETAMIDO-2-DESOXY-α-D-GALACTOPYRANOSYL)-D-GLUCOSE ET 3-O-α-D-TALOPYRANOSYL-D-GLUCOSE

Reduction of the primary alcohol group of 1,2:5,6-isopropylidene-3-O-(2,3,4-trideoxy-α-L-glycero-hex-2-enopyranosyl)-α-D-glucofuranose by p-toluenesulfonylation, substitution by iodine, and tributylstannane treatment, gave a 6'-deoxy derivative, which was