830335-30-3Relevant academic research and scientific papers
On the stereoselective bicyclization of aminodienes catalyzed by chelating diamide complexes of the group 3 metals. A direct comparison of Sc(iii) and Y(iii) bis(amide)s with an application to the synthesis of alkaloid 195F
Jiang, Tao,Livinghouse, Tom,Lovick, Helena M.
supporting information; experimental part, p. 12861 - 12863 (2012/02/02)
Highly diastereoselective bicyclizations of aminodienes catalyzed by chelating diamide complexes of Sc(iii) and Y(iii) that lead to pyrrolizidines and indolizidines are described. This bis(annulation) procedure has been utilized in a concise synthesis of the pyrrolizidine alkaloid 195F.
Stereoselective synthesis of substituted N-heterocycles via sequential cross metathesis-reductive cyclization
Gebauer, Julian,Dewi, Purnama,Blechert, Siegfried
, p. 43 - 46 (2007/10/03)
A diastereoselective synthesis of substituted piperidine and pyrrolidine derivatives is presented, employing a highly selective cross metathesis (CM) reaction followed by a domino reduction-cyclization process. A diastereoselective synthesis of substituted mono- and bicyclic-piperidine and pyrrolidine derivatives is presented, employing a highly selective cross metathesis (CM) reaction followed by a domino reduction-cyclization process.
