830335-32-5Relevant academic research and scientific papers
A mild and efficient tris(pentafluorophenyl)borane-catalyzed sakurai allylation of N-benzyloxycarbonylamino P-tolylsulfone with allyltrimethylsilane
Thirupathi, Ponnaboina,Neupane, Lok Nath,Lee, Keun-Hyeung
experimental part, p. 1275 - 1278 (2012/07/14)
Tris(pentafluorophenyl)borane, B(C6F5)3, was found to be an efficient catalyst for synthesis of N-Cbzhomoallylic amines using Sakurai allylation of N-benzyloxycarbonyl-amino p-tolylsulfones with allyltrimethylsilane.
A general and mild copper-catalyzed three-component synthesis of protected homoallyl amines
Pasunooti, Kalyan Kumar,Leow, Min Li,Vedachalam, Seenuvasan,Gorityala, Bala Kishan,Liu, Xue-Wei
scheme or table, p. 2979 - 2981 (2009/08/09)
A mild and highly efficient copper-catalyzed, one-pot, three-component reaction is developed for the synthesis of homoallyl amines. Reaction of an aldehyde, a carbamate, and allyltrimethylsilane in the presence of 5 mol % Cu(OTf)2 furnishes the corresponding protected homoallylic amines in good to excellent yields.
