83111-35-7Relevant academic research and scientific papers
CATALYTIC SYNTHESIS OF (η5-C5H5)Mn(CO)2(CNR) COMPLEXES AND THE CRYSTAL AND MOLECULAR STRUCTURE OF (η5-C5H5)Mn(CO)2(CNBut)
Harris, Gillian W.,Boeyens, Jan C.A.,Coville, Neil J.
, p. 87 - 94 (1983)
The complexes (η5-C5H5)Mn(CO)2(CNR) (R - But, C6H5CH2, C6H11, C6H3Me2-2,6, Me) are synthesized by the PdO catalysed thermal reaction between (η5-C5H5)Mn(CO)3 and RNC.The crystal and molecular structure of (η5-C5H5)Mn(CO)2(CNBut) has been determined by single crystal X-ray diffraction.In this structure the isonitrile ligand is bent away from the ring with a C-N-C angle of 172(2) deg.
