831215-58-8Relevant academic research and scientific papers
Chiral phosphine oxide BINAPO as a Lewis base catalyst for asymmetric allylation and aldol reaction of trichlorosilyl compounds
Kotani, Shunsuke,Hashimoto, Shunichi,Nakajima, Makoto
, p. 3122 - 3132 (2007/10/03)
Chiral phosphine oxide BINAPO, which was readily prepared from chiral phosphine BINAP, exhibited good catalytic activities in the reaction of trichlorosilyl compounds via hypervalent silicate intermediates. The allylation of aldehydes with allyltrichloros
Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes
Nakajima, Makoto,Kotani, Shunsuke,Ishizuka, Tadao,Hashimoto, Shunichi
, p. 157 - 159 (2007/10/03)
The effectiveness of chiral phosphine oxide BINAPO as a catalyst for the enantioselective addition of allyltrichlorosilanes to aldehydes was demonstrated, wherein the combination of diisopropylethylamine and tetrabutylammonium iodide as additives is cruci
