83124-61-2Relevant articles and documents
Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges
Nishino, Satoshi,Hosomi, Hiroyuki,Ohba, Shigeru,Matsushima, Hideaki,Tokii, Tadashi,Nishida, Yuzo
, p. 1509 - 1513 (2007/10/03)
Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.
