83150-88-3

Upstream product

• 106-22-9 Citronellol 

Downstream Products

• 83109-72-2 (E)-3,7-dimethyl-4-octen-1-ol tosylate 
• 83109-70-0 1-((E)-3,7-Dimethyl-oct-4-enyloxy)-4-nitro-benzene 
• 83109-69-7 1-((E)-3,7-Dimethyl-oct-4-enyloxy)-4-methoxy-benzene 
• 83109-65-3 1-Bromo-4-((E)-3,7-dimethyl-oct-4-enyloxy)-benzene 
• 83109-66-4 1-Chloro-4-((E)-3,7-dimethyl-oct-4-enyloxy)-benzene 
• 83109-68-6 1-((E)-3,7-Dimethyl-oct-4-enyloxy)-4-ethyl-benzene 
• 83109-67-5 1-((E)-3,7-Dimethyl-oct-4-enyloxy)-4-methyl-benzene 

Relevant academic research and scientific papers

CATALYTIC EXTENDED DOUBLE BOND MIGRATION WITH RETENTION OF CONFIGURATION: A "ZIP-REACTION"

(+) Citronellol was catalytically isomerized by Fe(CO)5 into (+) dihydrocitronellal with partial retention of configuration: the optical yield was 16 +/- 1 percent at 140 deg C.Isolation of partially isomerized intermediates and use of citronellol deuterated at various positions allowed a clear description of the reaction mechanism as a succession of 1,3 hydrogen shifts.The observed partial retention of configuration suggests that full 1,7 isomerization occurs before metal-olefin dissociation occurs even once.