83159-27-7 Usage
Uses
Used in Organic Chemistry:
(1aR,2S,5aR,8S,9aR,11R,11aR)-8-(Acetyloxy)-1a,2,3,4,5a,6,7,8,9,9a,10,11-dodecahydro-11-hydroxy-5a,9,9-trimethyl-13-methylene-5H-2,11a-ethanobenzo[5,6]cyclodec[1,2-b]oxirene-5,12-dione is used as a key intermediate in the synthesis of various organic compounds due to its unique structure and functional groups.
Used in Pharmaceutical Research:
This complex molecule is used in pharmaceutical research for the development of new drugs, given its potential to interact with biological targets and exhibit therapeutic effects. Its structural features may allow for the design of molecules with specific binding affinities and activities.
Used in Chemical Synthesis:
(1aR,2S,5aR,8S,9aR,11aR,11aR)-8-(Acetyloxy)-1a,2,3,4,5a,6,7,8,9,9a,10,11-dodecahydro-11-hydroxy-5a,9,9-trimethyl-13-methylene-5H-2,11a-ethanobenzo[5,6]cyclodec[1,2-b]oxirene-5,12-dione is utilized in chemical synthesis for creating novel compounds with potential applications in various industries, such as materials science, agrochemicals, and specialty chemicals.
Used in Analytical Chemistry:
(1aR,2S,5aR,8S,9aR,11R,11aR)-8-(Acetyloxy)-1a,2,3,4,5a,6,7,8,9,9a,10,11-dodecahydro-11-hydroxy-5a,9,9-trimethyl-13-methylene-5H-2,11a-ethanobenzo[5,6]cyclodec[1,2-b]oxirene-5,12-dione can be employed as a reference material or standard in analytical chemistry for the development and validation of analytical methods, given its well-defined structure and properties.
Used in Material Science:
(1aR,2S,5aR,8S,9aR,11aR,11aR)-8-(Acetyloxy)-1a,2,3,4,5a,6,7,8,9,9a,10,11-dodecahydro-11-hydroxy-5a,9,9-trimethyl-13-methylene-5H-2,11a-ethanobenzo[5,6]cyclodec[1,2-b]oxirene-5,12-dione may be used in material science for the development of new materials with unique properties, such as high thermal stability, chemical resistance, or specific optical characteristics.
Check Digit Verification of cas no
The CAS Registry Mumber 83159-27-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,1,5 and 9 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 83159-27:
(7*8)+(6*3)+(5*1)+(4*5)+(3*9)+(2*2)+(1*7)=137
137 % 10 = 7
So 83159-27-7 is a valid CAS Registry Number.
InChI:InChI=1/C22H30O6/c1-11-13-6-7-15(24)21(5)9-8-17(27-12(2)23)20(3,4)14(21)10-16(25)22(18(11)26)19(13)28-22/h13-14,16-17,19,25H,1,6-10H2,2-5H3/t13?,14-,16?,17+,19?,21?,22?/m1/s1
83159-27-7Relevant academic research and scientific papers
Asymmetric Total Syntheses of 8,9-Seco-ent-kaurane Diterpenoids Enabled by an Electrochemical ODI-[5+2] Cascade
Ding, Hanfeng,Gao, Beiling,Liu, Zhaobo,Tong, Zhenzhong,Wang, Bingnan
supporting information, p. 14892 - 14896 (2021/06/08)
An electrochemical ODI-[5+2] cascade reaction was developed which enables the rapid assembly of diversely functionalized bicyclo[3.2.1]octadienones from sensitive ethynylphenols. By combining a directed retro-aldol/aldol process, a [2,3]-sigmatropic rearr
Terpenoids. XLIX. Reactions of Shikoccin: Oxidation, Catalytic Reduction, and Conversion into the Abietane Skeleton
Fuji, Kaoru,Ito, Nozomu,Uchida, Itsuo,Fujita, Eiichi
, p. 1034 - 1037 (2007/10/02)
The Jones oxidation of shikoccin (1), the major diterpenoid of Rabdosia shikokiana var. occidentalis, unexpectedly provided products 3 and 4.Tetrahydroshikoccin (6) afforded the abietane-type compound 11 upon Jones oxidation.Keywords-shikoccin; Jones oxidation; ent-kaurane; abietane; Rabdosia shikokiana; Labiatae; epoxidation; diterpenoid
Terpenoids. XLVIII. New Diterpenoids from Rabdosia shikokiana var. occidentalis
Node, Manabu,Ito, Nozomu,Uchida, Itsuo,Fujita, Eiichi,Fuji, Kaoru
, p. 1029 - 1033 (2007/10/02)
Five new kaurene-type diterpenoids, shikoccin (1), O-methylshikoccin (2), epoxyshikoccin (3), O-methylepoxyshikoccin (4) and shikoccidin (5) were isolated from Rabdosia shikokiana var. occidentalis.All these compounds except for 5 possess a hitherto unknown 8,9-seco-ent-kaurene skeleton.Keywords-Rabdosia shikokiana; diterpenoid; shikoccin; shikoccidin; ent-kaurene; Labiatae
