83168-65-4

Usage

Uses

Used in Fluoropolymer Production:
(Z,Z)-(CF3CF=CF)2 is used as a monomer in the production of fluorinated polymers for their exceptional chemical and thermal stability, making them suitable for various applications, including non-stick coatings, electrical insulation, and corrosion-resistant materials.
Used in Refrigerant Industry:
(Z,Z)-(CF3CF=CF)2 is used as a refrigerant in the refrigeration and air conditioning industry due to its nonflammable nature and high chemical stability, ensuring safety and reliability in cooling systems.
Used in Industrial Applications:
(Z,Z)-(CF3CF=CF)2 is utilized in various industrial applications, such as the production of fire-fighting foams, lubricants, and cleaning agents, capitalizing on its unique properties like low toxicity and high stability.

InChI:InChI=1/C6F10/c7-1(3(9)5(11,12)13)2(8)4(10)6(14,15)16/b3-1-,4-2-

Upstream product

• 431-65-2 perfluoroallyl iodide 
• 89031-88-9 trans-perfluoro-3,4-dimethylcyclobutene 
• 102682-88-2 (E)-CF₃CFCFCu 
• 102682-82-6 (Z)-perfluoropropenyl iodide 

Relevant academic research and scientific papers

Transformations of F-Alkyl Iodides and Bromides Induced by Nickel(0) Carbonyl

Adducts of primary F-alkyl iodides with nickel carbonyl are formed readily in donor solvents and pyrolyze at 100-150 °C to give olefinic coupling products in high yield. The mechanism proposed to account for the observed chemistry involves preferential α-elimination of fluorine with formation of a carbenoid species complex coordinated to nickel. Differences in reaction paths among several types of substrate halides are rationalized on the basis of polarization of the Ni-C bond in the adducts. Support for these proposals is provided by state-of-the-art calculations.

Kinetic and Thermodynamic Studies of the Thermal Electrocyclic Interconversions of Perfluorinated Dienes and Cyclobutenes

Detailed kinetic and thermodynamic analyses were carried out for the thermal interconversions of (Z,Z)- and (E,E)-perfluoro-2,4-hexadienes with trans-perfluoro-3,4-dimethylcyclobutene, (E,Z)-perfluoro-2,4-hexadiene with perfluoro-cis-3,4-dimethylcyclobutene, (Z,Z)- and (E,E)-perfluoro-3,5-octadienes with trans-perfluoro-3,4-diethylcyclobutene, and (Z)- and (E)-perfluoro-1,3-pentadiene with perfluoro-3-methylcyclobutene.In each case the (Z,Z)- or (Z)-dienes exhibited substantial kinetic advantage over the (E,E)-or (E)-dienes in their cyclization precesses.