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The chemical compound "[Rh2Cl(CO)(tert-butyl isocyanide)2((diphenylarsino)(diphenylphosphino)methane)2]PF6" is a rhodium-based complex with a unique structure. It consists of two rhodium atoms, each bonded to a chlorine atom, a carbon monoxide (CO) ligand, and two tert-butyl isocyanide ligands. The rhodium atoms are also connected to two (diphenylarsino)(diphenylphosphino)methane ligands, which serve as chelating agents, forming a bridge between the two rhodium centers. The entire complex carries a positive charge, which is balanced by the presence of a hexafluorophosphate (PF6) counterion. [Rh2Cl(CO)(tert-butyl isocyanide)2((diphenylarsino)(diphenylphosphino)methane)2]PF6 is of interest in the field of organometallic chemistry and catalysis, particularly for its potential applications in homogeneous catalysis due to its well-defined structure and electronic properties.

83174-74-7

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83174-74-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 83174-74-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,1,7 and 4 respectively; the second part has 2 digits, 7 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 83174-74:
(7*8)+(6*3)+(5*1)+(4*7)+(3*4)+(2*7)+(1*4)=137
137 % 10 = 7
So 83174-74-7 is a valid CAS Registry Number.

83174-74-7Downstream Products

83174-74-7Relevant academic research and scientific papers

Synthesis and characterization of some rhodium(I) dimers containing (diphenylarsino)(diphenylphosphino)methane as the bridging ligand

Enlow, Paul D.,Woods, Clifton

, p. 64 - 68 (1983)

Binuclear Rh(I) complexes have been prepared by using the unsymmetrical bridging ligand (diphenylarsino)(diphenylphosphino)methane (DADPM). On the basis of infrared, 31P{1H} NMR, and 13C{1H} NMR data, the comple

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